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A. Graovac I. G Topological Approach to the Chemistry of (Paperback) (UK IMPORT)
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Item specifics
- Condition
- Book Title
- Topological Approach to the Chemistry of Conjugated Molecules
- Publication Name
- Topological Approach to the Chemistry of Conjugated Molecules
- Title
- Topological Approach to the Chemistry of Conjugated Molecules
- Format
- Trade Paperback
- EAN
- 9783540084310
- ISBN
- 9783540084310
- Edition
- Softcover reprint of the original 1st ed. 1977
- Publisher
- Springer Berlin / Heidelberg
- Genre
- Science Nature & Math
- Release Year
- 1977
- Release Date
- 01/08/1977
- Language
- English
- Country/Region of Manufacture
- DE
- Item Height
- 244mm
- Item Length
- 9.6in
- Series
- Lecture Notes in Chemistry Ser.
- Publication Year
- 1977
- Type
- Textbook
- Item Width
- 6.7in
- Item Weight
- 8.8 Oz
- Number of Pages
- X, 124 Pages
About this product
Product Information
"The second step is to determine constitution, Le. which atoms are bonded to which and by what types of bond. The result is ex pressed by a planar graph (or the corresponding connectivity mat rix) **** In constitutional formulae, the atoms are represented by letters and the bonds by lines. They describe the topology of the molecule." VLADIMIR PRELOG, Nobel Lecture, December l2;h 1975. In the present notes we describe the topological approach to the che mistry of conjugated molecules using graph-theoretical concepts. Con jugatedstructures may be conveniently studied using planar and connec ted graphs because they reflect in the simple way the connectivity of their pi-centers. Connectivity is important topological property of a molecule which allows a conceptual qualitative understanding, via a non numerical analysis, of many chemical phenomena or at least that part of phenomenon which depends on topology. This would not be possible sole ly by means of numerical (molecular orbital) analysis.
Product Identifiers
Publisher
Springer Berlin / Heidelberg
ISBN-10
3540084312
ISBN-13
9783540084310
eBay Product ID (ePID)
150594857
Product Key Features
Publication Name
Topological Approach to the Chemistry of Conjugated Molecules
Format
Trade Paperback
Language
English
Series
Lecture Notes in Chemistry Ser.
Publication Year
1977
Type
Textbook
Number of Pages
X, 124 Pages
Dimensions
Item Length
9.6in
Item Width
6.7in
Item Weight
8.8 Oz
Additional Product Features
Series Volume Number
4
Number of Volumes
1 Vol.
Lc Classification Number
Qd450-882
Table of Content
1. Introduction.- 2. Graphs in Chemistry.- 2.1. Basic Definitions and Concepts of Graph Theory.- 2.1.1. Definition of a Graph.- 2.1.2. The Adjacency Matrix of a Graph.- 2.1.3. Isomorphism of the Graphs.- 2.1.4. Further Characterization of a Graph.- 2.2. Graphs and Topology.- 2.2.1. Path, Length and Distance.- 2.2.2. Neighbours. The Invariants of a Graph.- 2.2.3. Ring and Oriented Ring. Regular and Complete Graphs. The Ring and the Edge Components of a Graph.- 2.2.4. Sachs Graphs with N Vertices.- 2.3. Graphs Representing Conjugated Molecules.- 2.3.1. Planar Graphs. Colouring of Graphs.- 2.3.2. Hückel Graphs.- 2.3.3. Trees. Benzenoid Graphs.- 2.4. Graph Spectrum. Sachs Theorem.- 2.4.1. Graph Spectrum.- 2.4.2. Graph Spectral Properties of Particular Classes of Graphs.- 2.4.3. Sachs Theorem.- 2.5. Topology and Simple Molecular Orbital Model.- 2.6. Application of the Coulson-Sachs Graphical Method.- 2.7. Extension of Graph-Theoretical Considerations to Möbius Structures.- 3. Total Pi-Electron Energy.- 3.1. Introduction.- 3.2. Identities And Inequalities.- 3.2.1. The Fundamental Identity.- 3.2.2. Relations Between Epi The Adjacency Matrix and the Density Matrix.- 3.2.3. The Loop Rule.- 3.2.4. Inequalities for Epi.- 3.3. The Coulson Integral Formula.- 3.3.1. The First Integral Formula.- 3.3.2. Further Coulson-Type Formulas. I.- 3.3.3. An Application of the Coulson Integral Formula: The Tree with Maximal Energy.- 3.3.4. Further Coulson-Type Formulae. II.- 3.3.5. A Class of Approximate Topological Formulas for Epi.- 3.4. Topological Factors Determining the Gross Part of Epi.- 3.5. The Influence of Cycles: The Hückel Rule.- 3.5.1. General Considerations.- 3.5.2. The Hückel Rule.- 3.5.3 An Application: The Hückel Rule for Annulenes.- 3.5.4. Extension of the Hückel Rule to Nonalternant Systems.- 3.6. The Influence of KekulÉ Structures.- 3.6.1. Structure Count and Algebraic Structure Count.- 3.6.2. The Basic Postulate of Resonance Theory.- 3.7. The Influence of Branching.- 3.7.1. Violation of the Basic Postulate of Resonance Theory.- 3.8. Summary.- 4. Resonance Energy.- 4.1. Introduction.- 4.2. Classical and Dewar Resonance Energies.- 4.3. Topological Resonance Energy.- 4.3.1. The Mathematical Basis.- 4.3.2. The Computation of the Acyclic Polynomial.- 4.4. Tre as a Criterion of Aromatic Stability. Correlation with Experimental Findings.- 4.5. Concluding Remarks.- 5. Reactivity of Conjugated Structures.- 5.1. Localization Energy.- 5.2. Dewar Number.- 5.3. Topological Approach to Localization Energy.- 5.4. Topological Aspect of Dewar Number.- 5.5. Nonbonding Molecular Orbitals.- 6. Conclusions.- 7. Literature.
Copyright Date
1977
Target Audience
Scholarly & Professional
Topic
Chemistry / Physical & Theoretical
Illustrated
Yes
Genre
Science
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