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Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and
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- Buy It NowIron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and
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eBay item number:395315635079
Item specifics
- Condition
- ISBN-13
- 9789819941209
- Type
- NA
- Publication Name
- NA
- ISBN
- 9789819941209
- Book Title
- Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers
- Book Series
- Springer Theses Ser.
- Item Length
- 9.3 in
- Publisher
- Springer
- Publication Year
- 2023
- Format
- Hardcover
- Language
- English
- Illustrator
- Yes
- Genre
- Technology & Engineering, Science
- Topic
- Materials Science / General, Chemistry / Physical & Theoretical, Chemistry / Industrial & Technical, Chemistry / Organic, Chemistry / General
- Item Width
- 6.1 in
- Item Weight
- 16 Oz
- Number of Pages
- Xiv, 153 Pages
About this product
Product Information
This thesis describes the development of iron-catalyzed thienyl C-H/C-H coupling. This is applied to the synthesis of highly conjugated and electron-rich thiophene compounds of interest in materials science by utilization of low redox potential of iron in combination with a mild oxalate oxidant. Transition-metal-catalyzed C(sp2)-H/C(sp2)-H coupling has attracted much attention as one of the most straightforward methods to construct C(sp2)-C(sp2) bonds. However, application of this ideal transformation to the synthesis of redox-sensitive pi-materials was hindered by the requirement of a strong oxidant for catalyst turnover. This limitation originates primarily from the large redox potential of conventional transition-metal catalysts such as palladium and rhodium. This thesis shows that the efficiency of C-H activation was significantly improved by introduction of a new conjugated tridentate phosphine ligand, giving direct access to polymeric thiophene materials from simple thiophene monomers. Considering the importance of environmentally friendly organic synthesis in terms of UN Sustainable Development Goals, the reactions described herein highlight the potential of iron, the most abundant transition-metal on earth, for the direct synthesis of functional small molecules and polymers of importance in energy device applications.
Product Identifiers
Publisher
Springer
ISBN-10
9819941202
ISBN-13
9789819941209
eBay Product ID (ePID)
16060718882
Product Key Features
Book Title
Iron-Catalyzed C-H/C-H Coupling for Synthesis of Functional Small Molecules and Polymers
Format
Hardcover
Language
English
Topic
Materials Science / General, Chemistry / Physical & Theoretical, Chemistry / Industrial & Technical, Chemistry / Organic, Chemistry / General
Publication Year
2023
Book Series
Springer Theses Ser.
Illustrator
Yes
Genre
Technology & Engineering, Science
Number of Pages
Xiv, 153 Pages
Dimensions
Item Length
9.3 in
Item Width
6.1 in
Item Weight
16 Oz
Additional Product Features
Number of Volumes
1 Vol.
Lc Classification Number
Qd410-412.5
Table of Content
1. General Introduction.- 2. Iron-Catalyzed Regioselective Thienyl C-H/C-H Homocoupling.- 3. Development of a Synthetic Method for Tridentate Phosphine Ligands.- 4. Iron-Catalyzed Regioselective Thienyl C-H/C-H Polycondensation.- 5. Iron-Catalyzed Oxidative C-H Alkenylation of Thiophenes with Enamines.- 6. Conclusions and Perspectives.
Copyright Date
2023
Dewey Decimal
547
Dewey Edition
23
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eBay item number:395315635079
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